華東理工大學

華東理工大學化學與分子學院碩士研究生導師信息介紹：馬海燕

教授 博士，博士生導師

電話：＋86 21 64253519

Email：haiyanma@ecust.edu.cn

2001年獲華東理工大學應用化學專業(yè)博士學位。于2001年5月赴德國留學深造，在烏爾姆大學Bernhard Rieger教授課題組進行博士后研究。2002年6月至2003年9月獲德國洪堡基金會資助在德國美茵茲大學化學系Jun Okuda教授課題組做客座研究，后繼續(xù)于德國亞琛工業(yè)大學無機化學研究所Jun Okuda教授研究組從事博士后研究工作。2005年6月回國，被聘為華東理工大學教授。迄今已在國內外核心學術期刊及國際會議上發(fā)表學術論文60余篇，被SCI收錄引用564次，他引近500余次，單篇最高被引110余次。所參與科研項目“新型高效、高選擇性茂鈦族金屬催化劑的分子設計、合成及催化行為研究”獲2004年上海市科技進步二等獎（第四完成人）。2006年獲上海市科技啟明星計劃、教育部新世紀優(yōu)秀人才支持計劃支持。完成及承擔多項國家自然科學基金項目及省部級科研項目�，F(xiàn)招收有機化學專業(yè)的碩士、博士研究生，以及工業(yè)催化專業(yè)的博士研究生。

目前承擔科研項目：

1）國家自然科學基金項目：分子內陰陽離子型鈣、鎂、鋅絡合物催化丙交酯立體選擇性聚合研究（2011.1.1～2012.12.30，總經費37萬）

2）國家自然科學基金項目：橋聯(lián)茚-芴鈦族絡合物催化丙烯高選擇性二聚研究（2013.1.1～2016.12.31，總經費78萬）

主要研究方向

1）新型過渡金屬絡合物的設計合成及應用于催化制備結構可控高性能聚烯烴。

設計及合成各種結構類型的過渡金屬有機化合物作為烯烴聚合催化劑。通過分子水平的催化劑結構設計來實現(xiàn)烯烴聚合、齊聚過程，聚烯烴結構的可控、可調（分子量，分子量分布，共聚單體分布，支化度，聚合物鏈立體規(guī)整性等），以獲得各種新型結構可控高性能聚烯烴材料。

2）新型主族及過渡金屬絡合物的設計合成及催化制備綠色環(huán)境友好聚合物材料的應用。
設計合成新型結構金屬催化劑如稀土、鋁、鈣、鎂等金屬的絡合物用于催化內酯等開環(huán)聚合。通過分子水平的催化劑結構設計、調控來實現(xiàn)對聚合物立體規(guī)整性、鏈結構的有序控制，獲得新型結構可控環(huán)境友好聚酯材料。

代表性論文：

1.Yuan Wang, Haiyan Ma*, “Exploitation of dinuclear salan aluminum complexes for versatile copolymerization of ε-caprolactone and L-lactide”, Chem. Commun., 2012, 48, 6729-6731.

2.Shaodi Song, Xingyu Zhang, Haiyan Ma*, Yang Yang, “Zinc complexes supported by claw-type aminophenolate ligands: synthesis, characterization and catalysis in the ring-opening polymerization of rac-lactide”, Dalton Trans., 2012, 41, 3266-3277.

3.Liying Wang, Haiyan Ma*, “Highly Active Magnesium Initiators for Ring-Opening Polymerization of rac-Lactide”, Macromolecules, 2010, 43, 6535-6537.

4.Liying Wang, Haiyan Ma*, “Zinc complexes supported by multidentate amino-phenolate ligands: synthesis, structure and catalysis in ring-opening polymerization of rac-lactide”, Dalton Trans., 2010, 39, 7897-7910.

5.Feng Qian, Keyin Liu, Haiyan Ma*, “Amidinate aluminum complexes: synthesis, characterization and ring-opening polymerization of rac-lactide”, Dalton Trans., 2010, 39, 8071-8083.

6.Shaogang Gong, Haiyan Ma*, Jiling Huang*, “Zirconium and hafnium complexes supported by linked bis(beta-diketiminate) ligands: synthesis, characterization and catalytic application in ethylene polymerization”, Dalton Trans., 2009, 8237-8247.

7.Bing Lian, Haiyan Ma, Thomas P. Spaniol, Jun Okuda, “Neutral and cationic aluminium complexes containing a chiral (OSSO)-type bis(phenolato) ligand: synthesis, structures and polymerization activity”, Dalton Trans., 2009, 9033-9042.

8.Shaogang Gong, Haiyan Ma*, Jiling Huang*, “Zirconium Complexes with Versatile β-Diketiminate Ligands: Synthesis, Structure, and Ethylene Polymerization”, J. Organomet. Chem., 2008, 693, 3509-3518.

9.Shaogang Gong, Haiyan Ma*, “-Diketiminate aluminium complexes: synthesis, characterization and ring-opening polymerization of cyclic esters”, Dalton Trans., 2008, 3345-3357.

10.Haiyan Ma, Thomas P. Spaniol, Jun Okuda, “Rare-Earth Metal Complexes Supported by 1,ω-Dithiaalkanediyl-Bridged Bis(phenolato) Ligands: Synthesis, Structure, and Heteroselective Ring-Opening Polymerization of rac-Lactide”, Inorg. Chem. 2008, 47, 3328-3339.

11.Haiyan Ma, Thomas P. Spaniol, Jun Okuda, “Highly heteroselective ring-opening polymerization of rac-lactide initiated by bis(phenolato) scandium complexes”, Angew. Chem. Int. Ed. Engl. 2006, 46, 7818-7821 (VIP article).

12.Haiyan Ma, Jun Okuda, “Kinetics and mechanism of L-lactide polymerization by rare earth metal silylamido complexes: the effect of alcohol addition”, Macromolecules, 2005, 38, 2665-2673.

13.Haiyan Ma, Gianluca Melillo, Leone Oliva, Thomas P. Spaniol, Ulli Englert, Jun Okuda, “Living polymerization of racemic lactide by aluminum initiators supported by tetradentate OSSO ligands”, Dalton Trans., 2005, 721-727.

14.Wigand Braune, Haiyan Ma, Thomas P. Spaniol, Jun Okuda, “Aluminum complexes with sulfide-linked bis(phenolato) ligands: the unusual structure and reactivity of the methyl bis(phenolato) complex [Al(tbmp)Me] (tbmp= 2, 2’-thiobis(6-tert-4-methylphenolato))”, Organometallics, 2005, 24, 1953-1958.

15.Haiyan Ma, Thomas P. Spaniol, Jun Okuda, “Rare earth metal complexes supported by 1, -dithiaalkanediyl-bridged bis(phenolato) ligands: synthesis, characterization and ring-opening polymerization catalysis of L-lactide”, Dalton Trans., 2003, 4770-4780.